Résumé :
|
Concentrations of heavy metals and various groups of organic microcontaminants were measured in zebra mussel and eel from the Rhine-Meuse basin. Residues in mussel from the Rhine and Meuse were on average 2.3 and 2.9 times higher than in those from the reference location of IJsselmeer. Total body burdens of organic microcontaminants in mussel and eel varied between 0.05 to 0.07 mmol/kg fat weight in six out of seven samples. The largest contribution in mussels and eel came from polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), respectively. Concentrations of bromodiphenylethers, chlorobenzenes, chloronitrobenzenes, chloroterphenyls, and chlorobenzyltoluenes were lower Total polybrominated biphenyl residues appear lower than total PCB levels. The largest chlorobiocide residues were noted for 4,4'-DDE, toxaphene, trichlorophenylmethane, and gamma-hexachlorocyclohexane. An extraordinary high body burden of 1.2 mmol/kg fat weight, largely consisting of acenaphthene, was observed in one sample. Ratios of concentrations in organism fat and dry organic suspended solids varied between 1 and 10 for traditionally monitored organochlorines, independent of the octanol-water partition coefficient (K-ow; for K-ow
|